111490-89-2Relevant academic research and scientific papers
DISPLACEMENT WITH NITROGEN NUCLEOPHILES AT C-3' of 7-AMINOCEPHALOSPORANIC ACID AND DERIVATIVES PROMOTED BY TRIALKYLSILYL TRIFLUOROMETHANESULPHONATES
Acton, David G.,Rogers, Kevin J.,Poyser, Philip J.
, p. 657 - 662 (2007/10/02)
Replacement of a 3'-acetate group of a cephem by an alkylamino group can be mediated by trialkylsilyl trifluoromethanesulphonates in dichloromethane or acetonitrile inter alia.Comparable yields to the more usual 3'-iodo routes have been achieved, using a
