111491-99-7

Basic information

• Product Name: Z-D-PipCH₃
• CAS NO: 111491-99-7
• Molecular Weight: 261.321
• Mol File: 111491-99-7.mol

Chemical Properties

• CAS DataBase Reference: Z-D-PipCH₃(CAS DataBase Reference)
• NIST Chemistry Reference: Z-D-PipCH₃(111491-99-7)
• EPA Substance Registry System: Z-D-PipCH₃(111491-99-7)

Safety Data

• Hazardous Substances Data: 111491-99-7(Hazardous Substances Data)

Upstream product

• 111491-95-3 Z-D-PipCH₂Cl 
• 111492-04-7 Z-D-PipCHN₂ 

Relevant articles and documents

α-Amino Ketones - A Contribution to the Synthesis of Optically Active Derivatives of Amino Acids and Peptides

The synthesis of N-Z-protected methyl ketones from amino acids via the chloromethyl ketones and dehalogenation of the latter with zinc in glacial acetic acid is described.Deprotection of the methyl ketones results in the formation of hydrohalogenides of the α-aminoalkyl methyl ketones further converted to N-acylated peptide ketones as analogs of peptide hormones or as competitively acting substrate analogs of proteolytic enzymes.Aminoacetone is conveniently prepared as well as methyl-pyrrolidyl ketone and methyl-piperidyl ketone.