111515-65-2Relevant academic research and scientific papers
NITRENES. SYNTHESIS OF UNSYMMETRICAL BIBENZYLS
Savin, V. I.
, p. 35 - 41 (2007/10/02)
A method was developed for the synthesis of unsymmetrical bibenzyls by thermolysis of the potassium salts of methanesulfonohydrazides in dimethyl sulfoxide in the presence of 1-pentanethiol.The yields of the unsymmetrical bibenzyls and their derivatives c
N-NITRENES. II. INVESTIGATION OF THE MECHANISM OF DISSOCIATION OF DIBENZYLAMINONITRENE BY CHEMICALLY INDUCED POLARIZATION OF 1H NUCLEI. THE SPIN STATE OF DIBENZYLAMINONITRENE
Savin, V. I.
, p. 15 - 25 (2007/10/02)
The mechanism of the dissociation of dibenzylaminonitrene and p-bromodibenzylaminonitrene into molecular nitrogen and hydrocarbon products was studied.Dibenzylaminonitrene forms dibenzyl and o- and p-benzyltoluenes.In the presence of thiophenol significant amounts of toluene are formed.During dissociation p-bromodibenzylaminonitrene gives a mixture of symmetrical and unsymmetrical dibenzyls.In the presence of octanethiol only unsymmetrical p-bromodibenzyl is formed.The dissociation of dibenzylaminonitrene takes place by synchronous cleavage of the two C-N bonds and the formation of a pair of benzyl radicals.Dibenzylaminonitrene dissociates from the singlet electronic state.
