1115271-75-4Relevant academic research and scientific papers
Dihedral-Angle-Controlled Crossover from Static Hole Delocalization to Dynamic Hopping in Biaryl Cation Radicals
Talipov, Marat R.,Navale, Tushar S.,Hossain, Mohammad M.,Shukla, Ruchi,Ivanov, Maxim V.,Rathore, Rajendra
, p. 266 - 269 (2016/12/30)
In cases of coherent charge-transfer mechanism in biaryl compounds the rates follow a squared cosine trend with varying dihedral angle. Herein we demonstrate using a series of biaryl cation radicals with varying dihedral angles that the hole stabilization
Octahydro[1,4:5,8]dimethanoanthraquinone as a cheap and readily available electron-transfer oxidant for biaryl synthesis from organocuprates
Shukla, Ruchi,Rathore, Rajendra
experimental part, p. 3769 - 3774 (2009/06/06)
The preparation of biaryls via oxidation of organocuprates with easily synthesized octahydro[1,4:5,8]dimethanoanthraquinone (DAQ) is described. The oxidative coupling of organocuprates using DAQ was successfully employed for the preparation of highly hind
