111564-38-6

Basic information

• Product Name: hanalpinol peroxide
• CAS NO: 111564-38-6
• Molecular Weight: 268.353
• Mol File: 111564-38-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: hanalpinol peroxide(CAS DataBase Reference)
• NIST Chemistry Reference: hanalpinol peroxide(111564-38-6)
• EPA Substance Registry System: hanalpinol peroxide(111564-38-6)

Safety Data

• Hazardous Substances Data: 111564-38-6(Hazardous Substances Data)

Upstream product

• 36577-33-0 (1R,3aS,8aS)-7-isopropyl-1,4-dimethyl-1,2,3,3a,6,8a-hexahydroazulene 

Downstream Products

• 94388-64-4 hanalpinol 

Relevant articles and documents

The Formation of Cyclic Peroxide from Guaia-6,9-diene as a Model for Hanalpinol Biosynthesis

Autooxidation and photosensitized oxidation converted guaia-6,9-diene into hanalpinol, both compounds are contained in the rhizomes of Alpinia japonica.This process may be considered to be a biomimetic conversion.Guaia-6,9-diene may be regarded as an immediate precursor of hanalpinol, and a biogenetic pathway has been proposed.The results of molecular orbital calculation (modified neglect of differential overlap (MNDO) method) supported this proposal and provided a basis for conformational analysis. Keywords---Alpinia japonica; guaia-6,9-diene; hanalpinol; biosynthesis; molecular orbital calculation; MNDO; autooxidation; photosensitized oxidation; conformational analysis