111569-40-5Relevant articles and documents
A NEW ROUTE TO IRON(0) THIOCARBONYL COMPLEX INVOLVING DESULPHURIZATION OF THE Fe(η2-CS2R)(1+) CATION WITH P-n-Bu3. CRYSTAL STRUCTURE OF Fe(CS)(CO)2(PPh3)2
Touchard, Daniel,Fillaut, Jean-Luc,Dixneuf, Pierre H.,Toupet, Loic
, p. 291 - 300 (1986)
Reaction of 2-CS2R)(CO)2(PPh3)2> (R = CH3, CH2Ph; X(1-) = PF6(1-), I(1-)) with P-n-Bu3 or PEt3 gives Fe(CS)(CO)2(PPh3)2 (3a); (ν(CS) 1235 cm-1; δ(13C) 324.28 ppm).The structure of 3a has been determined by X-ray diffraction.Crystal data are: a 18.821(5), b 12.113(3), c 18.149(5) Angstroem, β 117.76(6)deg, monoclinic, space group P21, Z = 4.The structure is a trigonal-bipyramid with equatorial CS group, trans PPh3 ligands, a Fe-C(S) bond distance of 1.768(8) and a C-S bond distance of 1.563(8) Angstroem.
Thiocarbonyl complexes of iron V. New thiocarbonyl complexes derived by substitution from Fe(CO)4CS
Petz, Wolfgang
, p. 397 - 402 (1988)
Reaction of Fe(CO)4CS (1) with PR3 (PR3 = PPh3, PPh2Me) in the presence of ONMe3 gives the substituted derivatives Fe(CO)3(CS)Pr3 (2) and Fe(CO)2(CS)(PR3)2 (3) in moderate yields.The compounds have been characterized by infrared, 13C, and 1H NMR spectrosc
