111583-36-9Relevant academic research and scientific papers
A New and Facile Synthesis of Ketene Imines and Their 2-Iminoazetidine Dimer from Nitriles via Their Nitrilium Salts
Fuks, Robert,Baudoux, Dominique,Piccinni-Leopardi, Carla,Declercq, Jean-Paul,Meerssche, Maurice Van
, p. 18 - 22 (2007/10/02)
A new one-pot synthesis of N-tert-butylketene imines 3 was accomplished on the basis of the reaction of N-tert-butylacetonitrilium tetrachloroferrate 2 with an organic base such as triethylamine or N-trisubstituted amidine 4.The α-hydrogen in 2 is particu
IMINOALKYLATION DES ENAMINES AVEC DES NITRILES VIA LE SEL DE NITRILIUM : UNE NUOVELLE METHODE DE SYNTHESE D'ENAMINOCETONES ET DE β-DICETONES
Baudoux, Dominique,Fuks, Robert
, p. 1009 - 1018 (2007/10/02)
The reaction of nitrilium salts with enamines leads to a mixture of enamines 4 and enaminoketones 5 by an iminoalkylation reaction.Partial hydrolysis of 4 with diluted acetic acid leads to the isolation of these new enaminoketones 5 in high yields.Refluxi
