111615-45-3Relevant academic research and scientific papers
An Oxy-Cope Approach to Hydroazulenoids. Synthetic and Mechanistic Aspects of Thermal Cyclization Reactions
Sworin, Michael,Lin, Ko-Chung
, p. 1815 - 1825 (2007/10/02)
The synthesis and thermal properties of C5-substituted oxy-Cope substrates are reported.In the trans-divinylcyclohexanol series, halomethyl substituents provided > 80percent isolated yield of the thermodynamically less stable cis-hydroazulenone 33 from ei
Cyclopentanoid Synthesis via the Intramolecular Trapping of Oxy-Cope Intermediates. Stereocontrolled Synthesis of the cis- and trans-Hydroazulene Skeleton
Sworin, Michael,Lin, Ko-Chung
, p. 5640 - 5642 (2007/10/02)
The -sigmatropic rearrangement of C5-substituted oxy-Cope derivatives was examined.With halomethyl groups the reaction sequence is efficiently directed to cyclopentanoid ring formation.
