1116153-74-2Relevant academic research and scientific papers
Radical additions of arenethiols to ynamides for the selective synthesis of N-[(Z)-2-(Arylsulfanyl)-1-alkenyl]amides
Sato, Akinori,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 570 - 576 (2010/09/05)
A variety of ynamides undergo highly regio- and stereoselective radical addition of arenethiols with the aid of trie- thylborane as a radical initiator. The products, N-[-2-arylsulfanyl-1 -alkenyl]amides, can be reduced with triethyl- silane in trifluoroa
Thieme Chemistry Journal Awardees - Where are they now? Regio- and stereoselective radical additions of thiols to ynamides
Sato, Akinori,Yorimitsu, Hideki,Oshima, Koichiro
experimental part, p. 28 - 31 (2009/06/06)
Regioselective and stereoselective radical additions of arenethiols to various ynamides have been developed. Mixing ynamides and arenethiols in the presence of a catalytic amount of triethylborane affords the corresponding adducts, (Z)-1-amino-2-thio-1-al
