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Vinyl Azides in Heterocyclic Synthesis. Part 5. Thermal and Photochemical Decomposition of Azidocinnamates Containing ortho-Cycloalkylidene Substituents
Moody, Christopher J.,Warrellow, Graham J.
, p. 913 - 920 (2007/10/02)
Heating the ortho-cycloalkylidene azidocinnamates (2b-e) in boiling toluene gives the indenotetrahydroazirines (8), derived by intramolecular ene reaction involving the C=N bond of the intermediate 2H-azirines (11), as the major product.The intramo
