1116532-03-6Relevant articles and documents
Synthesis of D- And L-carbocyclic nucleosides via rhodium-catalyzed asymmetric hydroacylation as the key step
Marce, Patricia,Diaz, Yolanda,Matheu, M. Isabel,Castillon, Sergio
supporting information; experimental part, p. 4735 - 4738 (2009/05/31)
(Chemical Equation Presented) D- and L-carbocyclic nucleosides were obtained by a new procedure involving an enantioselective rhodium/duphos- catalyzed hydroacylation reaction as the key step. The 3-hydroxymethyl- cyclopentanol intermediate was obtained by stereoselective reduction of ketone and by dynamic kinetic resolution (DKR).