111689-29-3Relevant academic research and scientific papers
Mn(III)-Based Oxidative Fragmentation-Cyclization Reactions of Unsaturated Cyclobutanols
Snider, Barry B.,Vo, Nha Huu,Foxman, Bruce M.
, p. 7228 - 7237 (2007/10/02)
Alylic cyclobutanols 1, 10, 21, 27, 32, 39, 51 and 58 are oxidatively fragmented by Mn(OAc)3*2H2O in EtOH to give tertiary radicals as shown in eq 1.These tertiary radicals undergo both 6-endo-cyclization to the α,β-unsaturated ketone to afford α-keto rad
