111735-22-9Relevant academic research and scientific papers
Aminoselenenylation of Alkanes: Syntheses of β-Phenylseleno Carbamates and β-Phenylseleno Cyanamides
Francisco, Cosme G.,Hernandez, Rosendo,Leon, Elisa I.,Salazar, Jose A.,Suarez, Ernesto
, p. 2417 - 2427 (2007/10/02)
β-(Phenylseleno)alkylcarbamates and β-(phenylseleno)alkylcyanamides have been synthesized in good yields by reaction of alkenes with carbamates and cyanamide, respectively, in presence of benzeneselenenyl chloride-silver tetrafluoroborate or N-phenylselenophthalimide-H+.The subsequent reductive or oxidative removal of the phenylseleno group affords alkylcarbamates and alkylcyanamides, and allylic carbamates, cyanamides, and cyanimides.
CONVERSION OF OLEFINS INTO FIVE-MEMBERED NITROGEN HETEROCYCLES BY RADICAL CYCLIZATION
Clive, Derrick L.J.,Mohammed, Ali Y.
, p. 1157 - 1167 (2007/10/02)
2-(Phenylseleno)alkyl cyanamides, available in one step from olefins, according to a known procedure, are easily alkylated on nitrogen by allylic and propargylic halides.The products undergo radical cyclization in the presence of a stannane to produce fiv
Cyanamidoselenenylation of Alkenes
Hernandez, Rosendo,Leon, Elisa I.,Salazar, Jose A.,Suarez, Ernesto
, p. 312 - 314 (2007/10/02)
The acid catalysed reaction of alkenes with N-phenylselenophthalimide and cyanamide affords β-phenylseleno cyanamides, which can be easily transformed into cyanamides, allylic cyanamides, or cyanimides.
