1117700-52-3Relevant academic research and scientific papers
Preparation of 1,2- and 1,4-dihydro derivatives of 6,7-dimethyl-2,3- diphenylquinoxaline via its dianion formed by reductive metallation
Kaban, Seniz,Aydogan, Feray
experimental part, p. 669 - 672 (2009/07/18)
Treatment of 6,7-dimethyl-2,3-diphenylquinoxaline with sodium in tetrahydrofuran formed a monomeric dianion. The chemical behavior of this dianion was investigated by a variety of reagents. As the result, alkylation reactions gave 1,2-dihydro derivatives, while acylation reactions occured at 1,4-positions. Annulation of the pyrazine ring system was accomplished by treating the dianion with oligomethylene dichlorides, Cl(CH2) n Cl, n = 2-4.
