1118-03-2 Usage
Description
AZIDOTRIMETHYLTIN is a chemical compound characterized by a tin atom bonded to three methyl groups and one azide group. It is primarily recognized for its role in organic chemistry, particularly in the synthesis of organotin compounds and the modification of organic molecules. Its reactivity in azide-alkyne cycloaddition reactions to form 1,2,3-triazole compounds is noteworthy. However, due to its high toxicity, AZIDOTRIMETHYLTIN must be handled with extreme care to avoid serious health risks.
Uses
Used in Organic Chemistry:
AZIDOTRIMETHYLTIN is used as a precursor in the synthesis of various organic compounds, playing a crucial role in the formation of organotin compounds and the alteration of organic molecules.
Used in Azide-Alkyne Cycloaddition Reactions:
In the field of chemical synthesis, AZIDOTRIMETHYLTIN is utilized as a reagent for azide-alkyne cycloaddition reactions, which are key processes in the creation of 1,2,3-triazole compounds, a class of molecules with diverse applications in chemistry and biology.
Used in Pharmaceutical and Chemical Research:
AZIDOTRIMETHYLTIN is employed in research settings for the development of new pharmaceutical agents and chemical entities, capitalizing on its unique reactivity and synthetic potential.
Check Digit Verification of cas no
The CAS Registry Mumber 1118-03-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,1,1 and 8 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 1118-03:
(6*1)+(5*1)+(4*1)+(3*8)+(2*0)+(1*3)=42
42 % 10 = 2
So 1118-03-2 is a valid CAS Registry Number.
InChI:InChI=1/3CH3.N3.Sn/c;;;1-3-2;/h3*1H3;;/q;;;-1;+1/rC3H9N3Sn/c1-7(2,3)6-5-4/h1-3H3
1118-03-2Relevant articles and documents
Ein einfaches Verfahren zur Herstellung von Organozinnaziden. Synthese und Struktur der sterisch gehinderten Stannylazide tBu3SnN3 und tBu2Sn(N3)2
Haenssgen, Dieter,Jansen, Martin,Leben, Christiane,Oster, Thomas
, p. 223 - 228 (1995)
Sterically crowded stannyl azides tBunSn(N3)4-n (IIa,b) have been prepared for the first time by the reactions of stannylamines tBunSn(NHR)4-n (Ia,b) with Me3SiN3 (a: n = 3, R = H; b: n = 2, R = tBu).The novel compounds were characterized by NMR (1H, 13C) and mass spectroscopy and their molecular structure determined by X-ray crystallography (IIa: space group P21/m, Z = 2; IIb: space group P21/n, Z = 4). Keywords: Tin; Stannyl azides; Synthesis; X-ray structure
Substituted imidazo-fused 6-membered heterocycles as angiotensin II antagonists
-
, (2008/06/13)
Substituted Imidazo-fused 6-membered heterocycles of structural formula: STR1 wherein A, B, C, and D are independently carbon atoms or nitrogen atoms are angiotensin II antagonists useful in the treatment of hypertension and congestive heart failure.
SUBSTITUTED PYRAZOLOPYRIMIDINES AS ANGIOTENSIN II ANTAGONISTS
-
, (2008/06/13)
Novel substituted pyrazolopyrimidines of formula (I) which are useful as angiotensin II antagonists, are disclosed. STR1