111826-11-0

Basic information

• Product Name: 2-(4-CHLOROPHENOXY)BENZALDEHYDE
• Synonyms: 2-(4-Chlorophenoxy)benzaldehyde 97%
• CAS NO: 111826-11-0
• Molecular Formula: C₁₃H₉ClO₂
• Molecular Weight: 232.67
• Product Categories: Aldehydes;C10 to C21;Carbonyl Compounds;Building Blocks;C13-C60;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
• Mol File: 111826-11-0.mol
• Article Data: 21

Chemical Properties

• Melting Point: 55-59 °C
• Boiling Point: 331.7 °C at 760 mmHg
• Flash Point: 136.9 °C
• Appearance: /
• Density: 1.266g/cm³
• Vapor Pressure: 0.000154mmHg at 25°C
• Refractive Index: 1.618
• Solubility: soluble in Toluene
• CAS DataBase Reference: 2-(4-CHLOROPHENOXY)BENZALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-CHLOROPHENOXY)BENZALDEHYDE(111826-11-0)
• EPA Substance Registry System: 2-(4-CHLOROPHENOXY)BENZALDEHYDE(111826-11-0)

Safety Data

• Hazard Codes: Xn,N
• Statements: 22-37/38-41-43-51/53
• Safety Statements: 26-36/37/39-61
• RIDADR: UN 3077 9/PG 3
• WGK Germany: 3
• HazardClass: IRRITANT
• Hazardous Substances Data: 111826-11-0(Hazardous Substances Data)

Usage

General Description

2-(4-chlorophenoxy)benzaldehyde is an organic compound with the chemical formula C13H9ClO2. It is a yellow crystalline solid with a floral, sweet, herbaceous odor. 2-(4-CHLOROPHENOXY)BENZALDEHYDE is used in the production of pharmaceuticals and agrochemicals as an intermediate for the synthesis of various substances. It is also used as a fragrance and flavoring agent in the food and beverage industry. Additionally, 2-(4-chlorophenoxy)benzaldehyde has been studied for its potential use in the development of new materials and as a building block for organic synthesis. The compound is considered to be relatively low in toxicity, but it should be handled with care and proper safety precautions.

InChI:InChI=1/C13H9ClO2/c14-11-5-7-12(8-6-11)16-13-4-2-1-3-10(13)9-15/h1-9H

Upstream product

• 25562-90-7 2-<4-Chlorphenyloxy>-benzylalkohol 
• 100-52-7 benzaldehyde 
• 106-48-9 4-chloro-phenol 
• 71730-46-6 benzo[e][1,2,3]oxathiazine 2,2-dioxide 
• 552-89-6 2-nitro-benzaldehyde 
• 446-52-6 2-Fluorobenzaldehyde 
• 1679-18-1 4-Chlorophenylboronic acid 

Downstream Products

• 29926-01-0 2-chloro-9H-xanthene 
• 13210-15-6 2-chloroxanthen-9-one 
• 2944-58-3 4-chlorophenyl 2-hydroxybenzoate 
• 1446253-83-3 (E)-methyl-3-(2-(4-chlorophenoxy)phenyl)acrylate 
• 1446253-21-9 (2E)-3-[2-(4-chlorophenoxy)phenyl]-N-hydroxy-2-propenamide 
• 25562-90-7 2-<4-Chlorphenyloxy>-benzylalkohol 
• 1393639-50-3 C₁₅H₁₄ClNO₂S 
• 2985-79-7 4'-chloro-2-hydroxybenzophenone 
• 1290052-71-9 (Z)-methyl 2-bromomethyl-3-[2-(4-chlorophenoxy)phenyl]propenoate 
• 1290052-63-9 methyl 3-[2-(4-chlorophenoxy)phenyl]-3-hydroxy-2-methylenepropanoate 
• 1184923-81-6 2-chloro-9-mesityl-9H-xanthene 

Relevant articles and documents

An umpoled synthon approach to the synthesis of 2-aryloxyphenols

A convenient three-step method for the preparation of 2-aryloxyphenols from phenols and 2-fluorobenzaldehyde is described. Condensation of phenols with 2-fluorobenzaldehyde produces the intermediate 2-aryloxybenzaldehydes in 83-95% yield. These products rapidly undergo meta-chloroperbenzoic acid (m-CPBA) promoted Baeyer-Villiger oxidation to yield the corresponding 2-aryloxyphenyl formates which are hydrolyzed, without isolation, to give the desired 2-aryloxyphenols in 79-96% yield.

Cerium-photocatalyzed aerobic oxidation of benzylic alcohols to aldehydes and ketones

We have developed a cerium-photocatalyzed aerobic oxidation of primary and secondary benzylic alcohols to aldehydes and ketones using inexpensive CeCl3 7H2O as photocatalyst and air oxygen as the terminal oxidant.

Pyrimidine onium compound and application thereof

The invention relates to a pyrimidine onium compound, nitride oxides, salt of the nitride oxides and a composition comprising the compound. The invention further relates to an application of the compound to plant pest control.