111833-35-3Relevant academic research and scientific papers
SYNTHESIS OF HOMOALLYLIC ALCOHOLS VIA PALLADIUM-CATALYZED COUPLING OF ORGANOMERCURIALS AND VINYLIC OXETANES
Larock, Richard C.,Stolz-Dunn, Sandra K.
, p. 5069 - 5072 (2007/10/02)
The reaction of aryl- and vinylmercurials, cupric chloride, 5percent aqueous NH4Cl, oxygen, catalytic amounts of Li2PdCl4 and vinylic oxetanes affords an excellent route to functionally-substituted homoallylic alcohols.
An Efficient and Stereoselectice Synthesis of Homoallykic Alcohols via Nickel-catalysed Coupling of 5-Alkyl-2,3-dihydrofurans with Grignard Reagents
Wadman, Sjoerd,Whitby, Richard,Yeates, Clive,Kocienski, Philip,Cooper, Kelvin
, p. 241 - 243 (2007/10/02)
The low-valent nickel-catalysed coupling of Grignard reagents with 5-alkyl-2,3-dihydrofurans is an efficient and stereoselective method for synthesising homoallylic alcohols provided appropriate care is taken in the workup.
