111865-49-7Relevant academic research and scientific papers
Allylstannane Allylation of Aldimines Activated by Chlorotrimethylsilane
Wang, De-Kun,Dai, Li-Xin,Hou, Xue-Long
, p. 8649 - 8652 (1995)
Aldimines activated by chlorotrimethylsilane reacted with allylstannane to give the corresponding homoallylic amines with excellent yields.
Allylation of Imines with in situ Generated Allyl Lead Reagents in a PbBr2/Al/BF3*OEt2/Et2O System
Tanaka, Hideo,Yamashita, Shiro,Ikemoto, Youichi,Torii, Sigeru
, p. 673 - 674 (1987)
Reductive addition of allyl bromide to imines has been performed with a combination of a catalytic amount of PbBr2 (0.03-0.1 equiv.) and Al (1 equiv.) in Et2O containing BF3*OEt2 (1.1 equiv.).
Mg and Zn mediated allylation of imines with allyl bromide
Wang, De-Kun,Dai, Li-Xin,Hou, Xue-Long,Zhang, Yi
, p. 4187 - 4188 (1996)
Both aldimines and ketamines are allylated under simple Barbier-type conditions using allyl bromide and commercial magnesium foil or zinc dust in tetrahydrofuran at room temperature.
A three-component synthesis of homoallylic amines catalyzed by CuI
Kalita, Pabitra Kumar,Phukan, Prodeep
, p. 5495 - 5497 (2008/12/22)
Cuprous iodide is a very effective catalyst for the three-component condensation of an aldehyde, benzylamine and allyltributylstannane in DMF to produce homoallylic amines in high yields.
Indium mediated Barbier-type allylation of aldimines in alcoholic solvents
Vilaivan, Tirayut,Winotapan, Chutima,Shinada, Tetsuro,Ohfune, Yasufumi
, p. 9073 - 9076 (2007/10/03)
Barbier-type allylation of unactivated aldimines with allyl bromides in the presence of indium powder took place rapidly in alcoholic solvents to give homoallylic amines in fair to good yields.
A NOVEL "Ti(0)" INDUCED ALLYLATION OF AMINES IN A TiCl4 (cat.)/ Al BIMETAL SYSTEM. CHIRALITY TRANSFER OF l-VALINE TO HOMOALLYLAMINE
Tanaka, Hideo,Inoue, Keizo,Pokorski, Ulrike,Taniguchi, Masatoshi,Torii, Sigeru
, p. 3023 - 3026 (2007/10/02)
"Barbier Type" allylation of imines with allyl bromide has been performed successfully by the action of aluminium (1 equiv.) and titanium(IV) chloride (0.05 equiv.) in THF.The chirality transfer of α-amino acid esters to homoallyl amines is demonstrated b
ELECTROREDUCTIVE "BARBIER TYPE" ALLYLATION OF IMINES WITH A COMBINATION OF A Pb(O)/Pb(II) REDOX MEDIATOR AND SACRIFICAL ANODE (Al)
Tanaka, Hideo,Nakahara, Takao,Dhimane, Hamid,Torii, Sigeru
, p. 4161 - 4164 (2007/10/02)
An electroreductive "Barbier Type" allylation of imines with allyl bromide has been performed in a PbBr2/Bu4NBr/THF-(Al anode)-(Pt cathode) system.A combination of Pb(O)/Pb(II) redox and a sacrifical aluminum anode works as a madiator for both cathodic an
