1118756-82-3Relevant academic research and scientific papers
Synthesis of the C9-C21 fragment of geldanamycin via a diastereoselective substrate-controlled hydrogenation
Horneff, Tony,Bach, Thorsten
scheme or table, p. 2969 - 2972 (2009/07/25)
An Ir-catalyzed diastereoselective hydrogenation was employed to establish the stereogenic center at carbon atom C14 of a C9-C21 fragment of geldanamycin. The fragment was stereoselectively synthesized from D-mannitol in 18 steps. Georg Thieme Verlag Stuttgart.
