111895-11-5

Basic information

• Product Name: Methanone, phenyl[2,3,4,5-tetramethyl-6-[(nitrooxy)methyl]phenyl]-
• CAS NO: 111895-11-5
• Molecular Formula: C18H19NO4
• Molecular Weight: 313.353
• Mol File: 111895-11-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanone, phenyl[2,3,4,5-tetramethyl-6-[(nitrooxy)methyl]phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, phenyl[2,3,4,5-tetramethyl-6-[(nitrooxy)methyl]phenyl]-(111895-11-5)
• EPA Substance Registry System: Methanone, phenyl[2,3,4,5-tetramethyl-6-[(nitrooxy)methyl]phenyl]-(111895-11-5)

Safety Data

• Hazardous Substances Data: 111895-11-5(Hazardous Substances Data)

Upstream product

• 20386-33-8 2,3,4,5,6-Pentamethylbenzophenone 

Relevant articles and documents

An Interpretation of the Puzzling Dichotomy of the Reaction Modes Observed during the Side-chain Nitration of Alkylaromatics

Nitration of substituted pentamethylbenzenes has been carried out under various conditions using the title nitrating systems in order to elucidate the peculiar dependence of the modes of side-chain substitution on the reagent employed; nitrooxylation with HNO3/CH2Cl2 and nitration with HNO3/(CH3CO)2O.Based on the evidence obtained from product variations with substituents, electrochemical nitrodecarboxylation of arylacetates, and ESR examination of the initial stage of the side-chain reactions, a proposal is made that the side-chain substitution of polysubstituted arenes occurs via a heterolytic path with HNO3/CH2Cl2 and via a homolytic path with HNO3/(CH3CO)2O.