111905-40-9Relevant academic research and scientific papers
Synthesis and characterization of (μ-R1C=NPh)(μ-RS)Fe2(CO)6 complexes
Seyferth, Dietmar,Hoke, Jeffrey B.
, p. 524 - 528 (2008/10/08)
New μ-iminoacyl complexes of the type (μ-R1C=NPh)(μ-RS)Fe2(CO)6 were prepared by the reactions of triiron dodecacarbonyl with thioimidates (R1C(SR)=NPh). The geometry of the bridging iminoacyl and thiolate ligands was determined primarily from IR and 13C NMR spectral correlations to related acyl and thioacyl systems. In related work, reaction of [Et3NH][(μ-Cp)(μ-RS)Fe2CO)6] with N-phenylbenzimidoyl chloride was found to be an alternate and superior route to complexes of this class.
