111931-16-9

Basic information

• Product Name: 3-(1-Methyl-1H-imidazol-2-yl)-1,5-diphenyl-penta-1,4-diyn-3-ol
• CAS NO: 111931-16-9
• Molecular Weight: 312.371
• Mol File: 111931-16-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(1-Methyl-1H-imidazol-2-yl)-1,5-diphenyl-penta-1,4-diyn-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(1-Methyl-1H-imidazol-2-yl)-1,5-diphenyl-penta-1,4-diyn-3-ol(111931-16-9)
• EPA Substance Registry System: 3-(1-Methyl-1H-imidazol-2-yl)-1,5-diphenyl-penta-1,4-diyn-3-ol(111931-16-9)

Safety Data

• Hazardous Substances Data: 111931-16-9(Hazardous Substances Data)

Upstream product

• 30148-21-1 ethyl 1-methyl-1H-imidazole-2-carboxylate 
• 4440-01-1 lithium phenylacetylide 

Relevant articles and documents

SYNTHESIS AND APPLICATION OF IMIDAZOLE DERIVATIVES. SYNTHESIS OF (1-METHYL-1H-IMIDAZOL-2-YL)METHANOL DERIVATIVES AND CONVERSION INTO CARBONYL COMPOUNDS

(1-methyl-2H-imidazol-2-yl)methanol derivatives ( 4 and 7 ) were prepared by treating carbonyl compounds with 2-lithio-1-methyl-1H-imidazole ( 2 ) or by treating 2-acyl-1H-imidazoles ( 3 ) with organometallic reagents or sodium borohydride.The alcohols ( 4 and 7 ) were convertible into the carbonyl compounds via the corresponding quaternary salts ( 8 and 10 ).The stable (1-methyl-1H-imidazol-2-yl)methanol system, , can be regarded as a masked form of the carbonyl group as well as a synthon of the group.Keywords - (1-methyl-1H-imidazol-2-yl)methanol; 2-acyl-1-methyl-1H-imidazole; carbonyl compound synthesis; β-ketoester; protecting group; latent functionality; symmetric ketone; dihydrojasmone