111940-36-4Relevant academic research and scientific papers
Stereoselective Formation of Three Carbon-Carbon Bonds by Cascade Reaction with Enolate Anion: Synthesis of Tricyclo1,6>dodecane and Tricyclo3,8>undecane Derivatives
Ihara, Masataka,Makita, Kei,Tokunaga, Yuji,Fukumoto, Keiichiro
, p. 6008 - 6013 (2007/10/02)
Reaction of 6--2-cyclohexen-1-one (1) with LHMDS, followed by one-pot treatment with CH2O, resulted in a cascade Michael-Michael-aldol reaction, producing hydroxymethylated tricyclo1,6>dodecane 3.The
Highly Stereocontrolled Construction of Tricyclo1,6>dodecanes by Intramolecular Double Michael Reaction
Ihara, Masataka,Toyota, Masahiro,Abe, Mariko,Ishida, Yohhei,Fukumoto, Keiichiro,Kametani, Tetsuji
, p. 1543 - 1550 (2007/10/02)
o-Anisaldehyde has been converted, via a sigmatropic reaction and a Birch reduction, into the cyclohexenone (10) bearing an α,β-unsaturated group.Treatment of the latter with lithium hexamethyldisilazide induced an intramolecular double Michael react
