111948-08-4

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 111948-17-5 (E/Z)-3-Methoxycarbonyl-2-methyl-2-propenylidenetriphenylarsorane 
• 19041-17-9 methyl 4-bromo-3-methylbut-2-enoate 
• 30626-03-0 (3E)-4-(4-chlorophenyl)-3-buten-2-one 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 
• 566188-46-3 (E/Z)-3-Methoxycarbonyl-2-methyl-2-propenyltriphenylarsonium bromide 

Relevant academic research and scientific papers

Peptide-catalyzed regio- and enantioselective reduction of α,β,γ,δ-unsaturated aldehydes

A resin-supported peptide catalyst (see box in the scheme) was used in the title reaction. The inherent regioselectivity was overcome by the peptide catalyst to promote the 1,6-selective reaction prior to 1,4-reduction. High stereoconvergence was also achieved when using a mixture of geometric isomers of the starting aldehydes. Ach=1-amino-1-cyclohexanecarboxylic acid. Copyright

The Use of an Arsorane as Isoprenoid Reagent: Synthesis of 5-Substituted 3-Methyl-2,4-pentadienoic Esters (ABA Ester Analogs)

By using of 3-methoxycarbonyl-2-methyl-2-propenylidenetriphenylarsorane (4) as isoprenoid reagent, 5-substituted 3-methyl-2,4-pentadienoic esters 6A and 6B (ABA ester analogs) were synthesized in 88-98percent yields under mild conditions.