111956-08-2Relevant academic research and scientific papers
Stereoselective Syntheses of Alcohols, XXVI. - Synthesis of 3-Methyl-2,6-dideoxyhexoses by Addition of an Allenyltitanium Reagent to Aldehydes.
Hoffmann, Reinhard W.,Lanz, Joachim W.,Metternich, Rainer
, p. 161 - 166 (2007/10/02)
In contrast to the nonregioselective addition of 3-methoxy-3-methylallenyllithium (8) to aldehydes the corresponding titanium reagent 14 produced only propargylic type adducts.The products resulting on addition of 14 to L-2-(benzyloxy)propionaldehyde have been converted into 3-O-methyl-3-methyl-2,6-dideoxyhexoses 23 and 25 of arabino and xylo configuration.
