111981-41-0

Upstream product

• 18826-96-5 4-amino-6-methyl-3-methylthio-1,2,4-triazin-5-one 
• 104-12-1 p-chlorphenylisocyanate 
• 109107-00-8 6-Methyl-3-(methylthio)-4-<(triphenylphosphoranylidene)amino>-5-oxo-4,5-dihydro-1,2,4-triazine 

Downstream Products

• 74-93-1 methylthiol 
• 96546-28-0 8-(4-chlorophenyl)-7-(4-chlorophenyl)-3-methyl<1,2,4>triazolo<5,1-c><1,2,4>triazin-4(8H)-one 
• 111969-36-9 4-(p-cnlorophenyl)-5-(p-chlorophenyl)amino-3-(6-methyl-3-methylthio-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)imino-2H-2,3-dihydro-1,2,4-triazole 
• 18826-96-5 4-amino-6-methyl-3-methylthio-1,2,4-triazin-5-one 
• 118458-73-4 C₃₀H₂₆Cl₃N₁₁O₂S₂ 
• 118458-75-6 C₃₁H₂₉Cl₂N₁₁O₃S₂ 
• 118458-72-3 C₃₂H₃₁Cl₂N₁₁O₃S₂ 
• 118458-77-8 1,3-bis-(p-chlorophenyl)-5-dimethylamino-2,4-bis-(6-methyl-3-methylthio-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)biguanide 
• 118458-68-7 C₂₆H₂₈Cl₂N₁₂O₂S₂ 
• 111969-44-9 1-methyl-4-(p-chlorophenyl)-5-(p-chlorophenyl)imino-3-(6-methyl-3-methylthio-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)imino-2H-2,3-dihydro-1,2,4-triazole 
• 111969-45-0 2-methyl-4-(p-chlorophenyl)-5-(p-chlorophenyl)amino-3-(6-methyl-3-methylthio-5-oxo-4,5-dihydro-1,2,4-triazin-4-yl)imino-2H-2,3-dihydro-1,2,4-triazole 
• 118458-66-5 C₂₇H₂₇Cl₂N₁₁O₂S₂ 
• 118458-64-3 C₂₅H₂₅Cl₂N₁₁O₂S₂ 
• 118543-28-5 4-[1-(4-Chloro-phenyl)-6-(4-chloro-phenylamino)-4-(4-nitro-phenyl)-1H-[1,3,5]triazin-(2Z)-ylideneamino]-6-methyl-3-methylsulfanyl-4H-[1,2,4]triazin-5-one 

Relevant academic research and scientific papers

Iminophosphorane-mediated Syntheses of Triazolotriazines. The Unexpected Formation of Z,Z-1,3-Diazetidine-2,4-di-imines. X-Ray Molecular Structure of 7-(p-Chloroanilino)-8-(p-chlorophenyl)-3-methyltriazolotriazin-4(8H)-one and of 1,3-Bis-(p-ch...

A number of triazolotriazine derivatives have been prepared. 6-Methyl-3-methylthio-4-triphenylphosphoranylideneamino-5-oxo-4,5-dihydro-1,2,4-triazine (19) reacts with aryl isocyanates to yield the corresponding 1,3-diaryl-2,4-bis-(6-methyl-3-methylthio-5-oxo-4,5-dihydro-1,2,4-triazin-4-ylimino)-1,3-diazetidines (20)-(24); these undergo ring cleavage on treatment with aqueous ethanol to give the 8-aryl-7-arylamino-3-methyltriazolotriazin-4(8H)-ones (8), (12), and (16)-(18).The reaction of the 3-arylmethylenehydrazino-6-methyl-5-oxo-4-triphenylphosphoranylideneamino-4,5-dihydro-1,2,4-triazines (35) and (36), available from the corresponding 4-amino-3-arylmethylenehydrazino-6-methyl-5-oxo-4,5-dihydro-1,2,4-triazine and triphenylphosphine dibromide, with alkyl or aryl isocyanates led directly to 7-arylamino-8-arylmethyleneamino-3-methyltriazolotriazin-4(8H)-ones (37)-(46).Also, iminophosphoranes (5)-(7), (35), and (36) react with acyl chlorides in the presence of triethylamine to give the triazolotriazinones (25)-(31) and (50)-(55) respectively.Structures of compounds (20)-(24) have been established by means of (13)C n.m.r. analysis and X-ray crystallography.