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Erucamide
Cas No: 112-84-5
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Erucylamide Manufacturer/High quality/Best price/In stock
Cas No: 112-84-5
USD $ 3.0-3.0 / Kilogram 1 Kilogram 1-100 Metric Ton/Month Dayang Chem (Hangzhou) Co.,Ltd. Contact Supplier
Erucamide
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No Data No Data No Data Chemwill Asia Co., Ltd. Contact Supplier
Factory price Cosmetic ERUCAMIDE 112-84-5 Manufacturer
Cas No: 112-84-5
USD $ 0.1-0.1 / Gram 1 Gram 100 Metric Ton/Year Xi'an Xszo Chem Co., Ltd. Contact Supplier
Factory Supply (Z)-docos-13-enamide
Cas No: 112-84-5
No Data 1 1 Ality Chemical Corporation Contact Supplier
(Z)-13-docosenamide
Cas No: 112-84-5
No Data 10 Milligram Amadis Chemical Co., Ltd. Contact Supplier
High quality Erucamide
Cas No: 112-84-5
USD $ 1.0-1.0 / Kilogram 25 Kilogram 50 Metric Ton/Day Hubei Jusheng Technology Co., Ltd., Contact Supplier
Manufacturer supply CAS 112-84-5 with best quality
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USD $ 139.0-210.0 / Kilogram 1 Kilogram 1000 Kilogram/Day Zhuozhou Wenxi import and Export Co., Ltd Contact Supplier
BLOOM TECH Advanced API/Technology support (Z)-Docos-13-enamide CAS 112-84-5
Cas No: 112-84-5
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Erucamide CAS NO.112-84-5
Cas No: 112-84-5
USD $ 1.0-3.0 / Kilogram 1 Kilogram 10 Kilogram/Day Hebei yanxi chemical co.,LTD. Contact Supplier

112-84-5 Usage

Chemical Properties

Solid. Soluble in isopropanol; slightly soluble in alcohol and acetone. Combustible.

Reference

B. van Lierop, L. Castle, A. Feigenbaum, A. Boenke, Spetra for the Identification of Additives in Food Packaging, 1998, ISBN 0-7923-4986-5 https://pubchem.ncbi.nlm.nih.gov/compound/Erucylamide#section=Use-and-Manufacturing https://www.sigmaaldrich.com/catalog/product/aldrich/280577?lang=de®ion=DE

Description

Cis-13-Docosenoamide is also known as Erucamide or Erucylamide. It is in the form of white flakes or beads. It is soluble in isopropanol, slightly soluble in alcohol and acetone.1 In industry, cis-13-docosenoamide is used in the formulations of anti-adhesive agents, lubricants, and lubricant additives to reduce their friction coefficient and to make films easier to handle.2 It is used as a standard to determine fatty acid amides in polyethylene packaging film by GC/MS.3

Uses

13-Docosenamide is the amide of docosenoic acid. It was first identified in the cerebrospinal fluid of sleep-deprived cats. It has also been detected in the cerebrospinal fluid of rats and humans. 13-Docosenamide causes reduced mobility and slightly lessened awareness in rats, whereas 9-octadecenamide induces physiological sleep.[Cayman Chemical]
InChI:InChI=1/C22H43NO/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18-19-20-21-22(23)24/h9-10H,2-8,11-21H2,1H3,(H2,23,24)/b10-9-

112-84-5 Well-known Company Product Price

Brand (Code)Product description CAS number Packaging Price Detail
USP (1545045)  Plastic additive 13  United States Pharmacopeia (USP) Reference Standard 112-84-5 1545045-100MG 4,647.24CNY Detail

112-84-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name (Z)-docos-13-enamide

1.2 Other means of identification

Product number -
Other names Unislip 1753

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Adhesives and sealant chemicals,Anti-adhesive agents,Lubricants and lubricant additives,Plating agents and surface treating agents,Processing aids, not otherwise listed
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:112-84-5 SDS

112-84-5Synthetic route

cis-13-docosenoic acid
112-86-7

cis-13-docosenoic acid

Unislip 1753
112-84-5

Unislip 1753

Conditions
ConditionsYield
With ammonia; zircornium(IV) n-propoxide at 165℃; for 6h; Reagent/catalyst;98.8%
Multi-step reaction with 2 steps
1: oxalyl dichloride / dichloromethane / Inert atmosphere
2: ammonium hydroxide
View Scheme
erucic acid chloride
59044-32-5, 7459-29-2

erucic acid chloride

Unislip 1753
112-84-5

Unislip 1753

Conditions
ConditionsYield
With ammonium hydroxide
Unislip 1753
112-84-5

Unislip 1753

cis-docos-13-enylamine
26398-95-8

cis-docos-13-enylamine

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 12h; Reflux;100%
Unislip 1753
112-84-5

Unislip 1753

erucyl alcohol
629-98-1

erucyl alcohol

Conditions
ConditionsYield
With samarium diiodide; water; triethylamine In tetrahydrofuran at 23℃; for 18h; Inert atmosphere; chemoselective reaction;94%
[hydroxy(tosyloxy)iodo]benzene
27126-76-7

[hydroxy(tosyloxy)iodo]benzene

Unislip 1753
112-84-5

Unislip 1753

cis-12-heneicosenylammonium tosylate
116749-38-3

cis-12-heneicosenylammonium tosylate

Conditions
ConditionsYield
In acetonitrile at 65 - 70℃; for 0.0333333h;63%
Unislip 1753
112-84-5

Unislip 1753

(3R)-N-{(3R,6R,9R,12S,15R,18S,19R)-6-(3-amino-3-oxopropyl)-15-[(2S)-butan-2-yl]-12-(4-hydroxybenzyl)-9-[(1R)-1-hydroxyethyl]-3,19-dimethyl-2,5,8,11,14,17-hexaoxo-1-oxa-4,7,10,13,16-pentaazacyclononadecan-18-yl}-15-carbamimidamido-3-hydroxypentadecanamide

(3R)-N-{(3R,6R,9R,12S,15R,18S,19R)-6-(3-amino-3-oxopropyl)-15-[(2S)-butan-2-yl]-12-(4-hydroxybenzyl)-9-[(1R)-1-hydroxyethyl]-3,19-dimethyl-2,5,8,11,14,17-hexaoxo-1-oxa-4,7,10,13,16-pentaazacyclononadecan-18-yl}-15-carbamimidamido-3-hydroxypentadecanamide

Conditions
ConditionsYield
Multi-step reaction with 9 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2.1: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
3.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 - 10 °C / Inert atmosphere
4.1: (R,R)-(η5-cyclopentadienyl)chloro[(4R,trans)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium / tetrahydrofuran; diethyl ether / 4 h / 0 - 20 °C
4.2: 16 h / -78 - 20 °C
5.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 13 h / 0 - 20 °C
5.2: 12 h / 20 °C
5.3: 120 h / Inert atmosphere
6.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
6.2: 12 h / -78 - 20 °C / Inert atmosphere
7.1: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 2 h / 20 °C
8.1: 4-methyl-morpholine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate / N,N-dimethyl-formamide / 0.08 h
8.2: 70 h / 20 °C
9.1: trifluoroacetic acid / dichloromethane; water / 1 h / 20 °C
View Scheme
Unislip 1753
112-84-5

Unislip 1753

9H-fluoren-9-ylmethyl (13Z)-docos-13-en-1-yl-carbamate

9H-fluoren-9-ylmethyl (13Z)-docos-13-en-1-yl-carbamate

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
View Scheme
Unislip 1753
112-84-5

Unislip 1753

9H-fluoren-9-yl-methyl (13-hydroxyhexadec-15-en-1-yl)carbamate

9H-fluoren-9-yl-methyl (13-hydroxyhexadec-15-en-1-yl)carbamate

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2.1: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
3.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 - 10 °C / Inert atmosphere
4.1: (R,R)-(η5-cyclopentadienyl)chloro[(4R,trans)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium / tetrahydrofuran; diethyl ether / 4 h / 0 - 20 °C
4.2: 16 h / -78 - 20 °C
View Scheme
Unislip 1753
112-84-5

Unislip 1753

di-tert-butyl [(E)-{[13-(methoxymethoxy)hexadec-15-en-1-yl]amino}methylylidene]biscarbamate

di-tert-butyl [(E)-{[13-(methoxymethoxy)hexadec-15-en-1-yl]amino}methylylidene]biscarbamate

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2.1: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
3.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 - 10 °C / Inert atmosphere
4.1: (R,R)-(η5-cyclopentadienyl)chloro[(4R,trans)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium / tetrahydrofuran; diethyl ether / 4 h / 0 - 20 °C
4.2: 16 h / -78 - 20 °C
5.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 13 h / 0 - 20 °C
5.2: 12 h / 20 °C
5.3: 120 h / Inert atmosphere
View Scheme
Unislip 1753
112-84-5

Unislip 1753

di-tert-butyl [(E)-{[13-(methoxymethoxy)-15-oxopentadecyl]amino}methylylidene]biscarbamate

di-tert-butyl [(E)-{[13-(methoxymethoxy)-15-oxopentadecyl]amino}methylylidene]biscarbamate

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2.1: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
3.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 - 10 °C / Inert atmosphere
4.1: (R,R)-(η5-cyclopentadienyl)chloro[(4R,trans)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium / tetrahydrofuran; diethyl ether / 4 h / 0 - 20 °C
4.2: 16 h / -78 - 20 °C
5.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 13 h / 0 - 20 °C
5.2: 12 h / 20 °C
5.3: 120 h / Inert atmosphere
6.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
6.2: 12 h / -78 - 20 °C / Inert atmosphere
View Scheme
Unislip 1753
112-84-5

Unislip 1753

di-tert-butyl [(E){[(13R)-15-({(3R,6R,9R,12S,15R,18S,19R)-6-(3-amino-3-oxopropyl)-15-[(2S)-butan-2-yl]-12-(4-hydroxybenzyl)-9-[(1R)-1-hydroxyethyl]-3,19-dimethyl-2,5,8,11,14,17-hexaoxo-1-oxa-4,7,10,13,16-pentaazacyclononadecan-18-yl}amino)-13-(methoxymethoxy)-15-oxopentadecyl]amino}methylylidene]biscarbamate

di-tert-butyl [(E){[(13R)-15-({(3R,6R,9R,12S,15R,18S,19R)-6-(3-amino-3-oxopropyl)-15-[(2S)-butan-2-yl]-12-(4-hydroxybenzyl)-9-[(1R)-1-hydroxyethyl]-3,19-dimethyl-2,5,8,11,14,17-hexaoxo-1-oxa-4,7,10,13,16-pentaazacyclononadecan-18-yl}amino)-13-(methoxymethoxy)-15-oxopentadecyl]amino}methylylidene]biscarbamate

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2.1: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
3.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 - 10 °C / Inert atmosphere
4.1: (R,R)-(η5-cyclopentadienyl)chloro[(4R,trans)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium / tetrahydrofuran; diethyl ether / 4 h / 0 - 20 °C
4.2: 16 h / -78 - 20 °C
5.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 13 h / 0 - 20 °C
5.2: 12 h / 20 °C
5.3: 120 h / Inert atmosphere
6.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
6.2: 12 h / -78 - 20 °C / Inert atmosphere
7.1: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 2 h / 20 °C
8.1: 4-methyl-morpholine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate / N,N-dimethyl-formamide / 0.08 h
8.2: 70 h / 20 °C
View Scheme
Unislip 1753
112-84-5

Unislip 1753

15-[N',N''-bis(tert-butoxycarbonyl)carbamimidamido]-3-(methoxymethoxy)pentadecanoic acid

15-[N',N''-bis(tert-butoxycarbonyl)carbamimidamido]-3-(methoxymethoxy)pentadecanoic acid

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2.1: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
3.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 - 10 °C / Inert atmosphere
4.1: (R,R)-(η5-cyclopentadienyl)chloro[(4R,trans)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato]titanium / tetrahydrofuran; diethyl ether / 4 h / 0 - 20 °C
4.2: 16 h / -78 - 20 °C
5.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 13 h / 0 - 20 °C
5.2: 12 h / 20 °C
5.3: 120 h / Inert atmosphere
6.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
6.2: 12 h / -78 - 20 °C / Inert atmosphere
7.1: 2-methyl-but-2-ene; sodium dihydrogenphosphate; sodium chlorite / water; tert-butyl alcohol / 2 h / 20 °C
View Scheme
Unislip 1753
112-84-5

Unislip 1753

9H-fluoren-9-yl-methyl (13-oxotridecyl)carbamate

9H-fluoren-9-yl-methyl (13-oxotridecyl)carbamate

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: lithium aluminium tetrahydride / tetrahydrofuran / 12 h / Reflux
2.1: sodium hydrogencarbonate / 1,4-dioxane; water / 14 h / 0 - 20 °C
3.1: ozone / dichloromethane / 0.5 h / -78 °C / Inert atmosphere
3.2: 0.5 h / -78 - 10 °C / Inert atmosphere
View Scheme

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