112010-92-1

Basic information

• Product Name: Benzeneacetamide, -alpha--hydroxy-2-(hydroxyphenylmethyl)-4,5-dimethoxy-
• Synonyms: Benzeneacetamide, -alpha--hydroxy-2-(hydroxyphenylmethyl)-4,5-dimethoxy-
• CAS NO: 112010-92-1
• Molecular Formula: C17H19NO5
• Molecular Weight: 317.34
• Mol File: 112010-92-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzeneacetamide, -alpha--hydroxy-2-(hydroxyphenylmethyl)-4,5-dimethoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetamide, -alpha--hydroxy-2-(hydroxyphenylmethyl)-4,5-dimethoxy-(112010-92-1)
• EPA Substance Registry System: Benzeneacetamide, -alpha--hydroxy-2-(hydroxyphenylmethyl)-4,5-dimethoxy-(112010-92-1)

Safety Data

• Hazardous Substances Data: 112010-92-1(Hazardous Substances Data)

Relevant articles and documents

Hydroxyiminoisoquinolin-3(2H)-ones. Part 7. Rearrangement of 4-Hydroxyimino-1,4-dihydroisoquinolin-3(2H)-ones under Wolff-Semmler-Type Reaction Conditions

The refluxing of 1-aryl-4-hydroximino-1,4-dihydroisoquinolin-3(2H)-ones (1 a-e) with Beckmann's mixture (AcOH/Ac2O/HCl) resulted in a hitherto unknown rearrangement to give 4-acetylamino-1-arylisoquinolin-3(2H)-ones (2 a-e).At 55 deg C, the 6,7-dimethoxy derivatives (1c) and (1d) yielded 3,4-dioxo-1-phenyl-1,2,3,4-tetrahydroisoquinolin-1-ol (6) and its N-methyl derivative (7), respectively.Reduction of these compounds with sodium borohydride caused cleavage of the hetero ring to give the acid amides (8) and (9).From the reactions at 95 deg C of the 6,7-dimethoxy derivative (1d) the oxazoloisoquinoline (10) was isolated.