112011-75-3Relevant academic research and scientific papers
Oxidative Addition of H2 and HCl to Iridium Sulfur Monoxide and Sulfur Dioxide Complexes
Schenk, Wolfdieter A.,Leissner, Johanna
, p. 967 - 971 (2007/10/02)
Square planar iridium(I) complexes of sulfur monoxide and sulfur dioxide undergo oxidative addition with dihydrogen and hydrogen chloride.The resulting hydrido-iridium(III) complexes have been characterized by 1H, 31P NMR and IR spectroscopy.The limited stability of the sulfur monoxide derivatives is explained as resulting from decreased back-bonding between iridium and sulfur. - Keywords: Sulfur Monoxide, Sulfur Dioxide, Oxidative Addition, Hydrido Iridium Complexes
