112014-65-0Relevant academic research and scientific papers
FLAVANOID PART 7 : A NOVEL PHOTOSYNTHESIS OF 3-α-HYDROXYBENZYLFLAVONES FROM 3-ARYLIDENEFLAVANONES
Dhande, V.P.,Thakwani (nee Joshi), Poonam,Marathe, K.G.
, p. 3015 - 3024 (2007/10/02)
E-3 Arylideneflavanones 4 on UV irradiation using quartzware undergo auto-oxidation to 3-aroylflavones 5.Photolysis using pyrex filter in the presence of iodoform furnishes 3-α-hydroxybenzylflavones indicating the intermediacy of the hydroperoxide 11 and form a new general method for the synthesis of these compounds not available by other routes.
Flavonoids. Part 6. The Kinetics and Mechanism of Base-catalysed Isomerisation of 3-Arylideneflavanones
Dhavale, Dilip Dattatraya,Joshi, Poonam,Marathe, Keshav Gangadhar
, p. 449 - 452 (2007/10/02)
Base-catalysed Z->E conversion of 3-arylideneflavanones provide a unique system suitable for kinetic studies by 1H n.m.r. spectroscopy.Isomerisation studies of 10 enones in pyridine showed that a first-order unimolecular reaction was taking place.The
