112033-42-8

Basic information

• Product Name: 4-CYCLOPROPYLAMINONAPHTHALENE
• Synonyms: 4-CYCLOPROPYLAMINONAPHTHALENE
• CAS NO: 112033-42-8
• Molecular Formula: C13H13 N
• Molecular Weight: 183.25
• Mol File: 112033-42-8.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 339.0±11.0 °C(Predicted)
• Appearance: /
• Density: 1.203±0.06 g/cm3(Predicted)
• PKA: 4.52±0.20(Predicted)
• CAS DataBase Reference: 4-CYCLOPROPYLAMINONAPHTHALENE(CAS DataBase Reference)
• NIST Chemistry Reference: 4-CYCLOPROPYLAMINONAPHTHALENE(112033-42-8)
• EPA Substance Registry System: 4-CYCLOPROPYLAMINONAPHTHALENE(112033-42-8)

Safety Data

• Hazardous Substances Data: 112033-42-8(Hazardous Substances Data)

Upstream product

• 765-30-0 Cyclopropylamine 
• 90-13-1 1-Chloronaphthalene 
• 99747-74-7 1-naphthyl triflate 
• 931081-80-0 N-cyclopropyl-2-(1-naphthyloxy)acetamide 
• 90-11-9 1-Bromonaphthalene 
• 134-32-7 1-amino-naphthalene 

Relevant articles and documents

Dirhodium(II)-Catalyzed (3 + 2) Cycloaddition of the N-Arylaminocyclopropane with Alkene Derivatives

Several (3 + 2) cycloaddition reactions catalyzed by dirhodium(II) complexes between N-arylaminocyclopropane and alkenes derivative have been developed. Preliminary mechanism studies suggest that dirhodium(II) complexes may decrease the bond-dissociation

Photoinduced electron injection into DNA by N-cyclopropyl-1- aminonaphthalene

DNA containing either N-cyclopropyl-1-aminonaphthalene (cAN) or N-methyl-1-aminonaphthalene (mAN) as a photoinduced electron donor have been developed to investigate the electron injection and charge recombination processes in DNA duplex. Oxidation potentials of the photo-excited aminonaphthalenes (ANs) were estimated to be approximately -3.0 V vs. SCE, which are high enough to induce one-electron reduction of DNA bases. Photoinduced excess electron transfer in the AN-tethered DNA duplexes has been examined using gel electrophoresis, but the apparent electron-transfer efficiencies were almost the same for both of the cAN- and the mAN-tethered DNA. The marginal effect of cyclopropyl substitution on the efficiency of charge separation suggests that charge recombination in the contact radical ion pair is faster and more efficient than cyclopropane-ring opening.

Asymmetric synthesis of cyclic β-amino carbonyl derivatives by a formal [3 + 2] photocycloaddition

Herein, a visible-light mediated strategy unlocking a family of cyclic β-amino carbonyl derivatives bearing three contiguous stereogenic centres is introduced. The overall reactivity relies on the performance of the substrate-catalyst complex to assist both the enantiocontrol and the photoredox tasks. This transformation led to an enantioselective [3 + 2] photocycloaddition between coordinated α,β-unsaturated acyl imidazoles and cyclopropylamine derivatives. This journal is

Nickel-Catalyzed N-Arylation of Cyclopropylamine and Related Ammonium Salts with (Hetero)aryl (Pseudo)halides at Room Temperature

Whereas the metal-catalyzed C(sp2)-N cross-coupling of cyclopropylamine with aryl electrophiles represents an attractive route to pharmaceutically relevant N-arylcyclopropylamines, few catalysts that are capable of effecting such transformation