112036-06-3

Basic information

• Product Name: 6-nitro-4,4'-dihydroxy-3,3'-dimethylbiphenyl
• Synonyms: 6-nitro-4,4'-dihydroxy-3,3'-dimethylbiphenyl
• CAS NO: 112036-06-3
• Molecular Weight: 259.262
• Mol File: 112036-06-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 6-nitro-4,4'-dihydroxy-3,3'-dimethylbiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 6-nitro-4,4'-dihydroxy-3,3'-dimethylbiphenyl(112036-06-3)
• EPA Substance Registry System: 6-nitro-4,4'-dihydroxy-3,3'-dimethylbiphenyl(112036-06-3)

Safety Data

• Hazardous Substances Data: 112036-06-3(Hazardous Substances Data)

Upstream product

• 95-48-7 ortho-cresol 

Relevant articles and documents

Hydroxylation of Alkylphenols by Cerium(IV) in Conjunction with Peroxide and Sodium Dodecyl Sulphate

Hydroxylation of alkylphenols has been achieved by oxidation with cerium(IV) ammonium nitrate in conjunction with hydrogen peroxide in sodium dodecyl sulphate medium; concurrent oxidation of alkyl groups and subsequent decarboxylation have also been observed in some cases.

Reaction of cerium(IV) ammonium nitrate with simple phenols in a silica gel matrix

The oxophilicity of cerium(IV) ammonium nitrate is moderated by the addition of hydrogen peroxide.The reaction with simple phenols becomes regioselective when carried out in a silica gel matrix.The methodology has been employed for the synthesis of new functionalized terphenyls and biphenyls.

Synthesis of Nitrobis- and Nitrotris-cresols Using Cerium (IV) Ammonium Nitrate

Cerium (IV) ammonium nitrate (CAN) has been conveniently employed for the first time to obtain nitro substituted bis- and tris-cresols which are otherwise obtained via lengthy and difficult routes.This is the first report on one-pot and one-step synthesis of oxidatively coupled cresols.Plausible mechanism for the reaction involved has also been suggested.