112036-07-4

Basic information

• Product Name: 4,4'-dihydroxy-3,3'-dimethyl-5,5'-dinitrodiphenyl
• Synonyms: 4,4'-dihydroxy-3,3'-dimethyl-5,5'-dinitrodiphenyl
• CAS NO: 112036-07-4
• Molecular Weight: 304.259
• Mol File: 112036-07-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 4,4'-dihydroxy-3,3'-dimethyl-5,5'-dinitrodiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4'-dihydroxy-3,3'-dimethyl-5,5'-dinitrodiphenyl(112036-07-4)
• EPA Substance Registry System: 4,4'-dihydroxy-3,3'-dimethyl-5,5'-dinitrodiphenyl(112036-07-4)

Safety Data

• Hazardous Substances Data: 112036-07-4(Hazardous Substances Data)

Upstream product

• 95-48-7 ortho-cresol 

Relevant articles and documents

Cerium(IV) induced oxidative coupling of simple phenols in the presence and absence of hydrogen peroxide: A comparative study of product distribution

The reaction of cerium(IV) ammonium nitrate with simple phenols (2-, 3- and 4-methylphenols) has been examined in the presence and absence of hydrogen peroxide.It has been observed that though the oxophilicity of cerium(IV) can be controlled by addition of hydrogen peroxide in the reaction medium, there is also a difference in the nature of products formed.The reaction can be used to obtain new terphenyls (3a, 3b and 3e), biphenyls (2a, and 2e), 2-hydroxy-1,9-dimethyl-7-nitro-dibenzyl-p-dioxin (4) and 3,7-dimethyl-1,9-dinitrodibenzofuran (5) in acceptable net yields.

Synthesis of Nitrobis- and Nitrotris-cresols Using Cerium (IV) Ammonium Nitrate

Cerium (IV) ammonium nitrate (CAN) has been conveniently employed for the first time to obtain nitro substituted bis- and tris-cresols which are otherwise obtained via lengthy and difficult routes.This is the first report on one-pot and one-step synthesis of oxidatively coupled cresols.Plausible mechanism for the reaction involved has also been suggested.