112069-30-4Relevant academic research and scientific papers
Regioselective Acylation of Terpene Hydrocarbons via Allyl- and Benzyltin Derivatives
Andrianome, M.,Delmond, B.
, p. 542 - 545 (1988)
Regioselective acylation of allyl- and benzylstannane derivatives derived from unsaturated terpene hydrocarbons are realized by a rhodium-catalyzed coupling with acyl halides.Mono- and sesquiterpenoid ketones which play an important role in the fragrance
ALLYL- AND BENZYLSTANNANES, NEW REAGENTS IN TERPENIC SYNTHESIS
Andrianome, M.,Haeberle, K.,Delmond, B.
, p. 1079 - 1088 (1989)
Terpenic allyl- and benzylstannanes are easily prepared from unsaturated terpene hydrocarbons by metallation followed by quenching with trialkyltin chloride.An isomerization of unsaturated terpenes via allyltin compounds is reported, by which (+)-α-pinene has been converted into (+)-β-pinene.A regioselective acylation of allyl- and benzylstannanes are realized by a rhodium-catalyzed coupling with acyl halides.Mono- and sesquiterpenoid ketones which play an important role in the fragrance industry can be obtained.Hydroxylation and oxidation of terpene hydrocarbons via allyl- and benzylstannanes are also reported.
