112093-64-8Relevant academic research and scientific papers
Methyl 2-(Benzyloxycarbonylamino)-2-cyclopropylideneacetate: A versatile building block for Cyclopropyl-Containing Amino Acids
Limbaeh, Michael,Lygin, Alexander,Es-Sayed, Mazen,De Meijere, Armin
experimental part, p. 1357 - 1364 (2009/07/26)
Methyl 2-(benzyloxycarbonylamino)-2-cyclopropylideneacetate (2) was prepared in nine steps starting from L-serine in an overall yield of 24 %. It has been demonstrated to be reasonably reactive in Michael additions of various nucleophiles (6 examples, 75-
Synthesis of 2,3-Methano-glutamic and -pyroglutamic Acid
Elrod, Luther F.,Holt, Elizabeth M.,Mapelli, Claudio,Stammer, Charles H.
, p. 252 - 253 (2007/10/02)
2,3-Methano-analogues of glutamic and pyroglutamic acid have been synthesized and the β-naphthylamide of the latter is shown to be stable to pyroglutamic amino peptidase; the crystal structure of the methyl pyroglutamate analogue has been determined.
