112128-28-6Relevant articles and documents
IMINATION OF SULFUR-CONTAINING COMPOUNDS. XXVIII. ARYLSULFONYLIMINATION OF SODIUM SALTS OF DIACYLMETHYL ARYL SULFIDES
Koval', I. V.,Panasenko, T. G.,Minyaev, R. M.,Panchenko, I. S.
, p. 288 - 290 (2007/10/02)
The use of their sodium salts instead of diacylmethyl aryl sulfides in arylsulfonylimination leads to an increase in the reactivity of the compounds toward the sodiochloroamides of sulfonic acids.As shown by quantum-mechanical calculations, this is due to the enhanced electron density at the sulfur atom on account of the displacement of electronic charge from the carbanionic center.
