112156-67-9Relevant academic research and scientific papers
Synthesis of 1-(2-Hydroxyaryl)-1,2,3-propanetriol and 1-(2-Hydroxyaryl)-2-amino-1,3-propanediol Derivatives of either threo or erythro Configuration
Casiraghi, Giovanni,Cornia, Mara,Rassu, Gloria
, p. 4919 - 4922 (2007/10/02)
The title arylglycerols 3A and 4A and arylaminopropanediols 3B and 4B, in either optical series (D or L) and with either configuration (threo or erythro), were prepared in optically pure form by direct arylation of 2,3-O-isopropylidene-D- or -L-glyceralde
Highly Regio- and Stereo-selective Synthesis of 1-(2-Hydroxyaryl)glycerol Derivatives under Ultrasonic Irradiation
Casiraghi, Giovanni,Cornia, Mara,Casnati, Giuseppe,Fava, Giovanna Gasparri,Belicchi, Marisa Ferrari,Zetta, Lucia
, p. 794 - 796 (2007/10/02)
Complementary diastereoselectivity in the C-arylation of (R)- and (S)-2,3-O-isopropylideneglyceraldehyde by using Mg2+-based (syn-addition) and Ti4+-based (anti-addition) phenolates allows the efficient preparation of all four possible stereoisomers of the title 1-C-substituted glycerols; the application of ultrasonic waves produces a marked synthetic advantage.
