112196-23-3Relevant academic research and scientific papers
Silicon-mediated synthesis of selenoaldehydes and selenoacylsilanes and their hetero diels-alder reactions
Degl'innocenti, Alessandro,Capperucci, Antonella,Acciai, Miriam,Tiberi, Caterina
, p. 1621 - 1626 (2009)
Bis(trimethylsilyl)selenide (HMDSS) reacts efficiently with aldehydes in the presence of CoCl2.6H2O to afford selenoaldehydes, which are trapped as Diels-Alder adducts by different dienes. The reaction can be applied to acylsilanes, to afford selenoacylsilanes, isolated as their cycloadducts.
