112247-22-0Relevant academic research and scientific papers
Efficient Synthesis of Methyl 2-(tert-Butyl)acrylate and Analogous Esters
Xu, Long-He,Kuendig, Ernst Peter
, p. 1480 - 1484 (1994)
The title products are prepared via an efficient three-step synthesis which involves hydroalumination of methyl propiolate and Lewis-acid-promoted reaction with acetone in the presence of BF3 followed by two highly selective SN2' reactions.The
Copper-Catalyzed One-Pot Borylative Aldolisation β-Fluoride Elimination for the Formal Addition of Acrylates to Carbonyl Moieties
Rasson, Corentin,Stouse, Adrien,Boreux, Arnaud,Cirriez, Virginie,Riant, Olivier
, p. 9234 - 9237 (2018/06/04)
Herein, we report the copper-catalyzed domino borylation/aldolisation of methyl 2-fluoroacrylate with carbonyl compounds followed by an elimination to give Morita–Baylis–Hillman (MBH) analogues. The optimal conditions described were shown to be compatible
Samarium (II) iodide-induced intermolecular coupling of a,b-unsaturated esters with ketones: Reactions of methyl propiolate and ethyl buta-2,3-dienoate with cyclohexanone and its application to synthesis of a terpene carboxylic acid
Sono, Masakazu,Doi, Natsuki,Yoshino, Eri,Onishi, Sachiko,Fujii, Daiki,Tori, Motoo
supporting information, p. 1947 - 1950 (2013/04/10)
The reactions of methyl propiolate and ethyl buta-2,3-dienoate with cyclohexanone induced by SmI2 occurred either at a- or b-position to yield different products depending on with or without a proton source. The synthesis of terpenic acid was demonstrated using this reaction.
Generation of aluminum and Aluminum Allenoates by the Hydroalumination of α,β-Acetylenic Carbonyl Compounds and Their Reaction with Carbonyl Compounds
Tsuda, Tetsuo,Yoshida, Tsutomu,Saegusa, Takeo
, p. 1037 - 1040 (2007/10/02)
aluminum and aluminum allenolate intermediates were generated by the hydroalumination of α,β-acetylenic ester and ketone, respectively, with DIBAH-HMPA.The aluminum generated from methyl propynoate reacte
