112247-56-0Relevant academic research and scientific papers
Highly stereoselective synthesis of 2,3-unsaturated thioglycopyranosides employing molecular iodine
Reddy, Basi V. Subba,Divyavani,Yadav, Jhillu S.
experimental part, p. 1617 - 1620 (2010/06/20)
Molecular iodine has been utilized for the first time for the thioglycosidation of d-glycals with various thiols to afford the corresponding 2,3-unsaturated thioglycosides in high yields. In the case of tri-O-acetyl-d-glucal, the -anomer was obtained exclusively. The use of readily available iodine makes this method quite simple, more convenient, and practical. Georg Thieme Verlag Stuttgart.
Regioselective Synthesis of Substituted 1-Thiohex-2-enopyranosides
Dunkerton, Lois V.,Adair, Nancy K.,Euske, Jack M.,Brady, Kevin T.,Robinson Paul D.
, p. 845 - 850 (2007/10/02)
A variety of 1-thiohex-2-enopyranosides have been prepared from their corresponding 3-O-methyl- or 3-O-acetylglycals by using trimethylsilyl thiols catalyzed by BF3 etherate.This method is regioselective for thiolation at C-1 in contrast to the same react
