1122593-50-3Relevant articles and documents
New 3π-2spiro ladder-type phenylene materials: Synthesis, physicochemical properties and applications in OLEDs
Cocherel, Nicolas,Poriel, Cyril,Rault-Berthelot, Joelle,Barriere, Frederic,Audebrand, Nathalie,Slawin, Alexandra M. Z.,Vignau, Laurence
, p. 11328 - 11342 (2008)
New routes to ladder-type phenylene materials 1 and 2 are described. The oligomers 1 and 2, which possess a "3π-2spiro" architecture, have been synthesized by using extended diketone derivatives 3 and 10 as key intermediates. The physicochemical properties of the new blue-light emitter 2 were studied in detail and compared with those of the less-extended 1. Owing to the recent development of fluorenone derivatives and their corresponding more conjugated analogues as potential electron-transport materials in organic light-emitting diodes (OLEDs) and as n-type materials for photovoltaic applications, we also report herein the thermal, optical and electrochemical behavior of the key intermediates, diketones 3 and 10. Finally, the application of dispiro 2 as a new light-emitting material in OLEDs is reported.