112272-50-1Relevant academic research and scientific papers
Stereoselective synthesis of vicinal dilithioalkenes by addition of lithium metal, to carbon-carbon triple bonds
Maercker,Girreser
, p. 8019 - 8034 (2007/10/02)
The reaction of various cyclic and acyclic alkynes with lithium dust (2% sodium) to form vicinal dilithioalkenes has been investigated. Aliphatic alkynes, e.g. 3-hexyne (27a), exclusively afford the corresponding (E)-dilithioalkenes, insoluble solids which are stable at room temperature and allow access to a variety of tetrasubstituted olefins in acceptable yields.
