112283-39-3

Basic information

• Product Name: (2R,5R)-7-Oxo-1-azabicyclo[3.2.0]heptane-2-carboxylic acid (4-nitrophenyl)methyl ester
• Synonyms: (2R,5R)-7-Oxo-1-azabicyclo[3.2.0]heptane-2-carboxylic acid (4-nitrophenyl)methyl ester
• CAS NO: 112283-39-3
• Molecular Formula: C14H14N2O5
• Molecular Weight: 290.27
• Mol File: 112283-39-3.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (2R,5R)-7-Oxo-1-azabicyclo[3.2.0]heptane-2-carboxylic acid (4-nitrophenyl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,5R)-7-Oxo-1-azabicyclo[3.2.0]heptane-2-carboxylic acid (4-nitrophenyl)methyl ester(112283-39-3)
• EPA Substance Registry System: (2R,5R)-7-Oxo-1-azabicyclo[3.2.0]heptane-2-carboxylic acid (4-nitrophenyl)methyl ester(112283-39-3)

Safety Data

• Hazardous Substances Data: 112283-39-3(Hazardous Substances Data)

Upstream product

• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 571200-58-3 (3S,5S)-carbapenam carboxylic acid benzyl ester 
• 1026369-94-7 C₂₂H₃₇NO₈ 
• 603127-33-9 (2S,5S)-5-Carboxymethyl-pyrrolidine-2-carboxylic acid methyl ester 
• 206128-03-2 (S)-dimethyl 2-(bis(tert-butoxycarbonyl)amino)pentanedioate 
• 192314-71-9 methyl (S)-2-N,N-di(tert-butoxycarbonyl)amino-5-oxopentanoate 
• 523988-38-7 (2S,5S)-1-azabicyclo[3.2.0]heptan-7-one-2-carboxylic acid methyl ester 
• 646505-03-5 (2S,5R)-1-Benzyl-5-tert-butoxycarbonylmethyl-pyrrolidine-2-carboxylic acid 4-nitro-benzyl ester 
• 646505-02-4 (S)-1-Benzyl-5-[1-tert-butoxycarbonyl-meth-(E)-ylidene]-pyrrolidine-2-carboxylic acid 4-nitro-benzyl ester 
• 131900-61-3 5-tert-butoxycarbonylmethyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 2-(4-nitro-benzyl) ester 
• 646505-05-7 5-tert-butoxycarbonylmethyl-pyrrolidine-1,2-dicarboxylic acid 1-tert-butyl ester 
• 131852-49-8 (2S,5R)-5-tert-Butoxycarbonylmethyl-pyrrolidine-2-carboxylic acid 
• 646505-06-8 (2S,5R)-5-Carboxymethyl-pyrrolidine-2-carboxylic acid 4-nitro-benzyl ester 
• 75468-46-1 p-nitrobenzyl 5(R)-carbapen-2-em-3-carboxylate 

Relevant articles and documents

Convenient syntheses of (3S,5S)-carbapenam-3-carboxylates and their biosynthetic relevance

Starting from readily available glutamate derivatives, facile stereoselective syntheses of (3S,5S)-carbapenam-3-carboxylates have been developed. Their significance in confirming the absolute configuration of the natural material is discussed.

Synthesis of (3S,5R)-Carbapenam-3-carboxylic Acid and Its Role in Carbapenem Biosynthesis and the Stereoinversion Problem

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The isolation and characterisation of (3R,5R)- and (3S,5R)-carbapenam-3-carboxylic acid from Serratia and Erwinia species and their putative biosynthetic role

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