112292-85-0Relevant academic research and scientific papers
MANGANESE (III) BASED OXIDATIVE FREE-RADICAL CYCLIZATIONS. 3. POLYCYCLIZATION REACTIONS PROCEEDING THROUGH SECONDARY RADICALS.
Mohan, Raju,Kates, Steven A.,Dombroski, Mark A.,Snider, Barry B.
, p. 845 - 848 (2007/10/02)
Oxidative cyclization of 3, 14, 18 and 21 with Mn(OAc)3.2H2O give the tricyclic products 6, 15, 19 and 23, respectively, in good yield.These reactions proceed through a monocyclic secondary radical which adds to the benzene ring prior to the second oxidation.
