112303-82-9Relevant academic research and scientific papers
Photolyses of Organocobaloxime Having Aralkyl and (Alkylthio)carbonyl Groups on the β-Position. A Radical Reaction Involving the Thioester Group
Tada, Masaru,Nakamura, Tatsuya,Matsumoto, Mitsuhiro
, p. 4647 - 4652 (2007/10/02)
-4-mesityl-2-methylbutyl>cobaloxime (1), -2-(ethoxycarbonyl)-5-phenylpentyl>cobaloxime (2), and -4-mesitylbutyl>cobaloxime (3) were photolyzed to produce pairs of organo radicals and
Photolyses of 2-(Alkylthio)carbonyl-2-(arylethyl) Cobaloxime
Tada, Masaru,Nakamura, Tatsuya,Matsumoto, Mitsuhiro
, p. 409 - 412 (2007/10/02)
2-(Alkythio)carbonyl-2-(arylethyl)propyl cobaloximes were photolyzed.When an aryl group is phenyl, a major process is a radical cyclization to give 2-(alkylthio)carbonyl-2-methyltetralin.On the other hand, β-thiolactone is a major product when an aryl group is mesityl and an alkyl group is t-butyl.
