112314-18-8

Basic information

• Product Name: <(1S)-(1,2,3/4,5)-2,3,4,5-tetrahydroxy-1-cyclohexanemethyl> β-D-glucopyranoside octa-acetate
• CAS NO: 112314-18-8
• Molecular Weight: 676.626
• Mol File: 112314-18-8.mol

Chemical Properties

• CAS DataBase Reference: <(1S)-(1,2,3/4,5)-2,3,4,5-tetrahydroxy-1-cyclohexanemethyl> β-D-glucopyranoside octa-acetate(CAS DataBase Reference)
• NIST Chemistry Reference: <(1S)-(1,2,3/4,5)-2,3,4,5-tetrahydroxy-1-cyclohexanemethyl> β-D-glucopyranoside octa-acetate(112314-18-8)
• EPA Substance Registry System: <(1S)-(1,2,3/4,5)-2,3,4,5-tetrahydroxy-1-cyclohexanemethyl> β-D-glucopyranoside octa-acetate(112314-18-8)

Safety Data

• Hazardous Substances Data: 112314-18-8(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 112314-17-7 Acetic acid (2R,3R,4S,5R,6R)-4,5-diacetoxy-6-acetoxymethyl-2-((3aS,4R,5aS,8aS,8bS)-2,2,7,7-tetramethyl-hexahydro-benzo[1,2-d;3,4-d']bis[1,3]dioxol-4-ylmethoxy)-tetrahydro-pyran-3-yl ester 

Downstream Products

• 52079-86-4 (1R)-(+)-(1,2,3/4,5)-2,3,4,5-tetrahydroxycyclohexane-1-methanol penta-acetate 
• 112314-19-9 <(1S)-(1,2,3/4,5)-2,3,4,5-tetrahydroxy-1-cyclohexanemethyl> β-D-glucopyranoside 
• 112314-19-9 (1R,2R,3R,4R,5S)-5-((2R,3R,4S,5S,6R)-3,4,5-Trihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxymethyl)-cyclohexane-1,2,3,4-tetraol 

Relevant articles and documents

SYNTHESIS OF SOME DERIVATIVES OF PSEUDO-α-GALACTOPYRANOSE

Isopropylidenation of DL-(1,2/3,4,5)-5-hydroxymethyl-1,2,3,4-cyclohexanetetrol (1) with 2,2-dimethoxypropane in N,N-dimethylformamide in the presence of toluene-p-sulfonic acid gave the 1,2:3,4-, 1,2:4,7-, and 2,3:4,7-di-O-isopropylidene derivatives.Several C-7 substituted derivatives of 1 of biological interest have been prepared by nucleophilic displacement reactions of the tosylate derived from the most readily avaible 1,2:3,4-di-O-isopropylidene derivative 3.Condensation of 3 with 2,3,4,6-tera-O-acetyl-α-D-glucopyranosyl bromide gave diastereoisomeric products, which were converted into 7-O-(β-D-glucopyranosyl)-pseudo-α-D- (26A) and -L-galactopyranose (26B), the structures of which were confirmed by degradation of the octa-acetate of 26A, yielding the know pseudo-α-D-galactopyranose penta-acetate.