112359-98-5Relevant academic research and scientific papers
Single-Molecule-Magnet FeII4FeIII2 and Antiferromagnetic FeIII4 Coordination Clusters
Barman, Suman K.,Cano, Joan,Lloret, Francesc,Mukherjee, Rabindranath
, p. 8086 - 8099 (2019)
Supported by endogenous (part of the ligand, in-built) phenoxo bridges provided by the ligand 2,6-bis[{{(5-bromo-2-hydroxybenzyl)}{(2-(pyridylethyl)}amino}methyl]-4-methylphenol) (H3L), in its deprotonated form, exogenous (not part of the ligan
Catalysis of alkene epoxidation by manganese(II) and (III) complexes of both Schiff base and reduced Schiff base ligands utilizing environmentally benign H2O2
Egekenze, Rita,Gultneh, Yilma,Butcher, Ray
, p. 198 - 209 (2018)
Mono and disubstituted tridentate Schiff base ligands were synthesized from the reaction of 2(2-aminoethyl)pyridine with 5-bromosalicylaldehyde (H-L1) and 3,5-dibromosalicylaldehyde (H-L2) respectively, which were subsequently reacte
Cytotoxic oxidovanadium(IV) complexes of tridentate halogen‐substituted Schiff bases: First dinuclear V(IV) complexes with O → VIV = O → VIV = O core
Aryaeifar, Mahnaz,Blacque, Olivier,Correia, Isabel,Marques, Fernanda,Micale, Nicola,Rudbari, Hadi Amiri,Saadati, Arezoo
supporting information, (2021/08/16)
The reaction of potentially N,N,O-tridentate Schiff base ligands, Cl-LH, Br-LH, BrCl-LH and H-LH, with [VIVO(acac)2] in 2:1 ratio in methanol gave the corresponding mononuclear and dinuclear oxidovanadium(IV) complexes, VO(Cl-L)
Synthesis, characterization, and formation constant of hexacoordinate iron(III) complexes
Asadi, Mozaffar,Hemmateenejad, Bahram,Mohammadikish, Maryam
experimental part, p. 124 - 135 (2010/09/10)
Twelve iron(III) complexes [FeIII(LX)2]ClO4, where (LX)- is the deprotonated form of a series of asymmetric ligands containing pyridine and substituted phenol moieties (XPh(OH)-CH=N-(CH2)n-Py that X = H, 5-Br, 5-NO2, 5-OMe, 4-OMe, 3-OMe, and n = 1, 2), were synthesized and characterized by H NMR, IR, UV-Vis spectroscopy, mass spectrometry, and elemental analysis. Formation constants were measured using UV-Vis spectrophotometric titration at constant ionic strength (0.10 M NaClO4) at 25 (±0.1)°C. The trend of the complex formation of Fe(III) ion with a given tridentate ligand decreases as follows: 5-OMe > 5-H > 5-NO2 > 5-Br 5-OMe > 4-OMe > 5-OMe.
