112379-21-2Relevant articles and documents
TANDEM RADICAL CYCLISATION - INTRAMOLECULAR MUKAIYAMA ALDOLISATION APPROACH TO FORSKOLIN
Hutchinson, John H.,Pattenden, Gerald,Myers, Peter L.
, p. 1313 - 1316 (1987)
The trans-decalin lactone (11), an advanced intermediate towards forskolin (1), has been elaborated in five steps from the bromo-acetal (4) using a novel stereoselective intramolecular radical mediated cyclisation reaction, viz. (4) -> (5), in tandem with
A NEW SYNTHETIC ROUTE TO (+/-)-FORSKOLIN
Begley, Michael J.,Cheshire, David R.,Harrison, Timothy,Hutchinson, John H.,Myers, Peter L.,et.al.
, p. 5215 - 5246 (2007/10/02)
The trans-decalin lactone (35) has been elaborated in five steps from the bromo-acetal (10) using a novel stereoselective intramolecular radical mediated cyclisation reaction, viz (10)->(12) in tandem with an intramolecular Mukaiyama aldolisation, viz (34
Photochemical Reactions 149. Photochemistry of 7,8-Dihydro-4-hydroxy-β-Ionone and Derivatives
Pascual, Alfons,Bischofberger, Norbert,Frei, Bruno,Jeger, Oskar
, p. 374 - 388 (2007/10/02)
The photolysis of 7,8-dihydro-4-hydroxy-β-ionone (6) was investigated together with its acetate and isopropyl ether 7 and 8, respectively.Irradiation (λ > 245 nm) of 6 in MeCN or i-PrOH at temperatures between 25 deg and -65 deg leads to the tricyclic eth