112379-36-9Relevant academic research and scientific papers
Intramolecular Nucleophilic Assistance at Tin: Reversal of Selctivity in SE2 Cleavage of Mixed Tetraorganotin Compounds by Iodine
Jousseaume, B.,Villeneuve, P.
, p. 513 - 514 (2007/10/02)
Electriphilic cleavage of mixed-functionality tetraorganotin compounds by iodine reveals a complete reversal of the usually observed selectivity; i.e. alkyltin-carbon bonds are broken in preference to aryl- or vinyl-tin-carbon bonds; this unexpected result is explained by intramolecular assistance at tin.
