112381-01-8Relevant academic research and scientific papers
Reactions of cyclopropanes with potassium dihaloiodates
Zyk,Gavrilova, A. Yu.,Bondarenko,Mukhina,Tikhanushkina
scheme or table, p. 340 - 354 (2011/06/23)
Reactions of potassium dihaloiodates with arylcyclopropanes and polycyclic compounds containing a cyclopropane fragment characterized by different degrees of strain lead to formation of mixed 1,3-halogenation products. If iodohalogenation should give rise to products having a iodine atom in the benzylic position, 1,3-dichloro or 1,3-dibromo derivatives are formed. Iodohalogenation of exo-tricyclo[3.2.1.02,4]octane is stereoselective and is accompanied by Wagner-Meerwein rearrangement.
1,3-Iodofunctionalization of Cyclopropanes by Means of the Mercury(II) Salt-Iodine Combination
Barluenga, Jose,Martinez-Gallo, Jose M.,Najera, Carmen,Yus, Miguel
, p. 582 - 584 (2007/10/02)
The reaction of phenylcyclopropane with iodine and various mercury(II) salts affords regiospecifically 1,3-bifunctionalized phenylpropanes following the Markownikoff rule; in the case of cyclopropyl phenyl ketone, the reaction with mercury(II) chloride-io
